Abstract

A history of allyl chloride production and alternative technologies is presented. The properties needed for use of this material are given and common reactions and reaction products are discussed. Manufacture and processing of allyl chloride is covered including discussion of the high temperature propylene chlorination reaction mechanism, significant reaction by-products, reaction conditions, industrial reactor design, product recovery through fractional distillation, and materials of construction. Techniques for maintenance of product integrity during storage and shipment are discussed, and transport equipment to maximize safety and minimize potential environmental impact is mentioned. Current production facilities for allyl chloride are listed. Most production is used for captive use as raw material for epichlorohydrin production. Sales specifications, statistical quality control parameters and analytical methods are briefly covered. Health hazards, exposure limits, personal protective equipment, and emergency response information are given. Current commercial products manufactured from allyl chloride are discussed.