Abstract
The technology for electroorganic synthesis is surveyed. Cell design and electrode materials, including the use of diaphragms in certain cases, are discussed, as are cell current distribution and mass-transport phenomena. Features influencing good product specificity with certain cell designs are presented, together with a sampling of commercially available cells. Cost analysis for electroorganic synthesis is reviewed. A number of electroorganic processes that have been commercialized or carried out at pilot-plant scale are presented.
Keywords: electrochemical processing; electrosynthesis; commercial processes; cell design; product recovery; adiponitrile; montan wax; small-scale processes; sebacic acid; perfluorinated compounds