{"id":304,"date":"2007-01-13T17:24:54","date_gmt":"2007-01-13T21:24:54","guid":{"rendered":"http:\/\/softbeam.net\/research\/?p=304"},"modified":"2007-01-13T17:24:54","modified_gmt":"2007-01-13T21:24:54","slug":"stereoselective-synthesis-of-trifluoromethylated-vicinal-ethylenediamines-with-r-amino-n-tert-butanesulfinimines-and-tmscf3","status":"publish","type":"post","link":"https:\/\/softbeam.net\/research\/?p=304","title":{"rendered":"Stereoselective Synthesis of Trifluoromethylated Vicinal Ethylenediamines with r-Amino N-tert-Butanesulfinimines and TMSCF3"},"content":{"rendered":"<p>By courtesy of:<br \/>\n<a href=\"http:\/\/20.210.105.67\/research\/wp-content\/uploads\/2007\/01\/jacs-02-stereoselective-synthesis-with-tmscf3.pdf\" id=\"p303\" onmousedown=\"selectLink(303);\">G. K. Surya Prakash* and Mihirbaran Mandal<\/a><br \/>\n<a href=\"http:\/\/20.210.105.67\/research\/wp-content\/uploads\/2007\/01\/jacs-02-stereoselective-synthesis-with-tmscf3.pdf\" id=\"p303\" onmousedown=\"selectLink(303);\">J. AM. CHEM. SOC. 2002, 124, 6538-6539<\/a><br \/>\nThe original one:<br \/>\n<a href=\"http:\/\/20.210.105.67\/research\/wp-content\/uploads\/2007\/08\/jacs-89-tmscf3.pdf\" title=\"jacs-89-tmscf3.pdf\">Fluoride-Induced Trifluoromethylation of Carbonyl Compounds with Trifluoromethyltrimethylsilane (TMS-CF3). A Trifluoromethide Equivalent<\/a><br \/>\n<a href=\"http:\/\/20.210.105.67\/research\/wp-content\/uploads\/2007\/08\/jacs-89-tmscf3.pdf\" title=\"jacs-89-tmscf3.pdf\">G. K. Surya Prakash,* Ramesh Krishnamurti, and George A. Olah*<\/a><br \/>\n<a href=\"http:\/\/20.210.105.67\/research\/wp-content\/uploads\/2007\/08\/jacs-89-tmscf3.pdf\" title=\"jacs-89-tmscf3.pdf\">J. Am. Chem. SOC. 1989, 111, 393-395<\/a><br \/>\nand the preparation of Ruppert reagent:<br \/>\n<a href=\"http:\/\/20.210.105.67\/research\/wp-content\/uploads\/2007\/08\/tl-84-ruppert-reagent.pdf\" title=\"tl-84-ruppert-reagent.pdf\">DIE ERSTEN CF3-SUBSTITUIERTEN ORGANYL(CHLOR)SILANE<\/a><br \/>\n<a href=\"http:\/\/20.210.105.67\/research\/wp-content\/uploads\/2007\/08\/tl-84-ruppert-reagent.pdf\" title=\"tl-84-ruppert-reagent.pdf\">Ingo Ruppert, * Klaus Schlich und Wolfgang Volbach<\/a><a href=\"http:\/\/20.210.105.67\/research\/wp-content\/uploads\/2007\/08\/tl-84-ruppert-reagent.pdf\" title=\"tl-84-ruppert-reagent.pdf\"> <\/a><br \/>\n<a href=\"http:\/\/20.210.105.67\/research\/wp-content\/uploads\/2007\/08\/tl-84-ruppert-reagent.pdf\" title=\"tl-84-ruppert-reagent.pdf\">T.L. 1984, 25, 2195<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>By courtesy of: G. K. Surya Prakash* and Mihirbaran Mandal J. AM. CHEM. SOC. 2002, 124, 6538-6539 The original one: Fluoride-Induced Trifluoromethylation of Carbonyl Compounds with Trifluoromethyltrimethylsilane (TMS-CF3). A Trifluoromethide Equivalent G. K. Surya Prakash,* Ramesh Krishnamurti, and George A. Olah* J. Am. Chem. SOC. 1989, 111, 393-395 and the preparation of Ruppert reagent: DIE &hellip; <a href=\"https:\/\/softbeam.net\/research\/?p=304\" class=\"more-link\">Continue reading<span class=\"screen-reader-text\"> &#8220;Stereoselective Synthesis of Trifluoromethylated Vicinal Ethylenediamines with r-Amino N-tert-Butanesulfinimines and TMSCF3&#8221;<\/span><\/a><\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[5,7],"tags":[],"class_list":["post-304","post","type-post","status-publish","format-standard","hentry","category-functionalization","category-soft"],"_links":{"self":[{"href":"https:\/\/softbeam.net\/research\/index.php?rest_route=\/wp\/v2\/posts\/304","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/softbeam.net\/research\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/softbeam.net\/research\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/softbeam.net\/research\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/softbeam.net\/research\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=304"}],"version-history":[{"count":0,"href":"https:\/\/softbeam.net\/research\/index.php?rest_route=\/wp\/v2\/posts\/304\/revisions"}],"wp:attachment":[{"href":"https:\/\/softbeam.net\/research\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=304"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/softbeam.net\/research\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=304"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/softbeam.net\/research\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=304"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}