{"id":438,"date":"2007-04-16T16:29:47","date_gmt":"2007-04-16T20:29:47","guid":{"rendered":"http:\/\/softbeam.net\/research\/?p=438"},"modified":"2007-04-16T16:29:47","modified_gmt":"2007-04-16T20:29:47","slug":"room-temperature-preparation-of-trifluoroethenylzinc-reagent-by-metalation-of-the-readily-available-halocarbon-hfc-134a-and-an-efficient-economically-viable-synthesis-of-122-trifluorostyrenes","status":"publish","type":"post","link":"https:\/\/softbeam.net\/research\/?p=438","title":{"rendered":"Room Temperature Preparation of Trifluoroethenylzinc Reagent by Metalation of the Readily Available Halocarbon HFC-134a and an Efficient, Economically Viable Synthesis of 1,2,2-Trifluorostyrenes"},"content":{"rendered":"

By courtesy of:
\nAnilkumar Raghavanpillai and Donald J. Burton*<\/a>
\nJ. Org. Chem. 2004, 69, 7083-7091<\/a>
\nalso:
\nRoom temperature preparation of a-chloro-b,b-difluoroethenylzinc reagent (CF2 CClZnCl) by the metallation of HCFC-133a (CF3CH2Cl) and a high yield one-pot synthesis of a-chloro-b,b-difluorostyrenes<\/a>
\nR. Anilkumar, Donald J. Burton*<\/a>
\nJournal of Fluorine Chemistry 126 (2005) 835\u00e2\u20ac\u201c843<\/a>
\nthe old one:
\nPalladium-Catalyzed Cross-Coupling of Perfluoroalkenylzinc Reagents with Aryl Iodides. A New, Simple Synthesis of cr,B,B-Trifluorostyrenes and the Stereoselective Preparation of 1-Arylperfluoropropenes<\/a>
\nPamela L. Heinze and Donald J. Burton*<\/a>
\nJ. Org. Chem. 1988,53, 2714-2720<\/a>
\nAnother paper by chinese:
\nThe spin-delocalization substituent parameter Part 10. The spin-delocalizing abilities of the paw-trifluorovinyl and para-acetoxy groups. Synthesis of parer-trifluorovinyl-, paravinyl- and para-acetoxy-a,b,b-trifluorostyrenes<\/a>
\nXi-Kui Jiang*, Guo-Zhen Ji*, Daniel Ze-Rong Wang<\/a>
\nJournal of Fluorine Chemistry 79 ( 1996) 173-178<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"

By courtesy of: Anilkumar Raghavanpillai and Donald J. Burton* J. Org. Chem. 2004, 69, 7083-7091 also: Room temperature preparation of a-chloro-b,b-difluoroethenylzinc reagent (CF2 CClZnCl) by the metallation of HCFC-133a (CF3CH2Cl) and a high yield one-pot synthesis of a-chloro-b,b-difluorostyrenes R. Anilkumar, Donald J. Burton* Journal of Fluorine Chemistry 126 (2005) 835\u00e2\u20ac\u201c843 the old one: Palladium-Catalyzed Cross-Coupling … Continue reading “Room Temperature Preparation of Trifluoroethenylzinc Reagent by Metalation of the Readily Available Halocarbon HFC-134a and an Efficient, Economically Viable Synthesis of 1,2,2-Trifluorostyrenes”<\/span><\/a><\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[5,7],"tags":[],"class_list":["post-438","post","type-post","status-publish","format-standard","hentry","category-functionalization","category-soft"],"_links":{"self":[{"href":"https:\/\/softbeam.net\/research\/index.php?rest_route=\/wp\/v2\/posts\/438","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/softbeam.net\/research\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/softbeam.net\/research\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/softbeam.net\/research\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/softbeam.net\/research\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=438"}],"version-history":[{"count":0,"href":"https:\/\/softbeam.net\/research\/index.php?rest_route=\/wp\/v2\/posts\/438\/revisions"}],"wp:attachment":[{"href":"https:\/\/softbeam.net\/research\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=438"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/softbeam.net\/research\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=438"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/softbeam.net\/research\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=438"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}