{"id":589,"date":"2007-08-31T15:16:44","date_gmt":"2007-08-31T19:16:44","guid":{"rendered":"http:\/\/softbeam.net\/research\/?p=589"},"modified":"2007-08-31T15:16:44","modified_gmt":"2007-08-31T19:16:44","slug":"selective-fluoroalkylations-with-fluorinated-sulfones-sulfoxides-and-sulfides","status":"publish","type":"post","link":"https:\/\/softbeam.net\/research\/?p=589","title":{"rendered":"Selective Fluoroalkylations with Fluorinated Sulfones, Sulfoxides, and Sulfides"},"content":{"rendered":"

By courtesy of:
\nG.K.Surya Prakash, Jinbo Hu<\/a>
\nAccounts of Chemical Research, 2007<\/a>
\nand some papers:
\nStereoselective Monofluoromethylation of Primary and Secondary Alcohols by Using a Fluorocarbon Nucleophile in a Mitsunobu Reaction<\/a>
\nG. K. Surya Prakash,* Sujith Chacko, Steevens Alconcel, Timothy Stewart, Thomas Mathew, and George A. Olah*
\n<\/a>
\n Angew. Chem. Int. Ed. 2007, 46, 4933 \u00e2\u20ac\u201c4936<\/a>
\nStereoselective Difluoromethylenation Using Me3SiCF2SPh: Synthesis of Chiral 2,4-Disubstituted 3,3-Difluoropyrrolidines<\/a>
\nYa Li and Jinbo Hu*<\/a>
\nAngew. Chem. Int. Ed. 2007, 46, 2489 \u00e2\u20ac\u201c2492<\/a>
\nA Remarkably Efficient Fluoroalkylation of Cyclic Sulfates and Sulfamidates with PhSO2CF2H: Facile Entry into b-Difluoromethylated or b-Difluoromethylenated Alcohols and Amines<\/a>
\nChuanfa Ni, Jun Liu, Laijun Zhang, and Jinbo Hu*<\/a>
\nAngew. Chem. Int. Ed. 2007, 46, 786 \u00e2\u20ac\u201c789<\/a>
\nFacile Synthesis of Chiral a-Difluoromethyl Amines from N-(tert-Butylsulfinyl)aldimines<\/a>
\nYa Li and Jinbo Hu*<\/a>
\nAngew. Chem. Int. Ed. 2005, 44, 5882 \u00e2\u20ac\u201c5886<\/a>
\nDifluoromethyl Phenyl Sulfone, a Difluoromethylidene Equivalent: Use in the Synthesis of 1,1-Difluoro-1-alkenes<\/a>
\nG. K. Surya Prakash,* Jinbo Hu, Ying Wang, and George A. Olah<\/a>
\nAngew. Chem. Int. Ed. 2004, 43, 5203 \u00e2\u20ac\u201c5206<\/a>
\nDifluoromethyl Phenyl Sulfone as a Selective Difluoromethylene Dianion Equivalent: One-Pot Stereoselective Synthesis of anti-2,2-Difluoropropane-1,3-diols<\/a>
\nG. K. Surya Prakash,* Jinbo Hu, Thomas Mathew, and George A. Olah<\/a>
\nAngew. Chem. Int. Ed. 2003, 42, 5216 \u00e2\u20ac\u201c5219<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"

By courtesy of: G.K.Surya Prakash, Jinbo Hu Accounts of Chemical Research, 2007 and some papers: Stereoselective Monofluoromethylation of Primary and Secondary Alcohols by Using a Fluorocarbon Nucleophile in a Mitsunobu Reaction G. K. Surya Prakash,* Sujith Chacko, Steevens Alconcel, Timothy Stewart, Thomas Mathew, and George A. Olah* Angew. Chem. Int. Ed. 2007, 46, 4933 \u00e2\u20ac\u201c4936 … Continue reading “Selective Fluoroalkylations with Fluorinated Sulfones, Sulfoxides, and Sulfides”<\/span><\/a><\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[5,7],"tags":[],"class_list":["post-589","post","type-post","status-publish","format-standard","hentry","category-functionalization","category-soft"],"_links":{"self":[{"href":"https:\/\/softbeam.net\/research\/index.php?rest_route=\/wp\/v2\/posts\/589","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/softbeam.net\/research\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/softbeam.net\/research\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/softbeam.net\/research\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/softbeam.net\/research\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=589"}],"version-history":[{"count":0,"href":"https:\/\/softbeam.net\/research\/index.php?rest_route=\/wp\/v2\/posts\/589\/revisions"}],"wp:attachment":[{"href":"https:\/\/softbeam.net\/research\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=589"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/softbeam.net\/research\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=589"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/softbeam.net\/research\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=589"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}