{"id":635,"date":"2007-10-08T21:18:29","date_gmt":"2007-10-09T01:18:29","guid":{"rendered":"http:\/\/softbeam.net\/research\/?p=635"},"modified":"2007-10-08T21:18:29","modified_gmt":"2007-10-09T01:18:29","slug":"recent-advances-in-nucleophilic-fluorination-reactions-of-organic-compounds-using-deoxofluor-and-dast","status":"publish","type":"post","link":"https:\/\/softbeam.net\/research\/?p=635","title":{"rendered":"Recent Advances in Nucleophilic Fluorination Reactions of Organic Compounds Using Deoxofluor and DAST"},"content":{"rendered":"

By courtesy of:
\nRajendra P. Singh, Jean\u00e2\u20ac\u2122ne M. Shreeve*
\nSynthesis 2002, 17, 2561<\/a>
\nand Olah’s reagent:
\nSynthetic Methods and Reactions. 63.\u00e2\u20ac\u2122 Pyridinium Poly( hydrogen fluoride) (30% Pyridine-70% Hydrogen Fluoride): A Convenient Reagent for Organic Fluorination Reactions
\nGeorge A. Olah,* John T. Welch, Yashwant D. Vankar, Mosatomo Nojima, Istvan Kerekes, and Judith A. Olah
\nJ. Org. Chem. 1979, 44, 3872<\/a>
\nand review on electrophilic fluorination:
\nRecent Highlights in Electrophilic Fluorination with 1-Chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane Bis(tetrafluoroborate)
\nRAJENDRA P. SINGH AND JEAN\u00e2\u20ac\u2122NE M. SHREEVE*
\nAcc. Chem. Res. 2004, 37, 31-44<\/a>
\nand about Selectfluor:
\nl-Alkyl-4-fluoro-l,4-diazoniabicyclo[2.2.2]octane Salts: a Novel Family of Electrophilic Fluorinating Agents
\nR. Eric Banks,* Suad N. Mohialdin-Khaffaf, G. Sankar Lal, Iqbal Sharif and Robert G. Syvret
\nJCS Chem Commun. 1992, 595<\/a>
\nand its commercialization by Air Product:
\nIndustrial scale production of Select\u00c2\u00afuorTM \u00c2\u00afuorination agent: from initial concept to full scale commercial production in a 5 year period
\nJames J. Hart, Robert G. Syvret*
\nJFC 1999, 100, 157<\/a>
\nand an advance from Alliedsignal, now Honeywell:
\nUS5459267<\/a>
\nand an example of electrophilic fluorination by NFSI:
\nSynthesis of difluorinated pyridinecarboxaldehyde via electrophilic fluorination
\nYoon-Joo Ko, Kyung-Bae Park, Seung-Bo Shim, Jung-Hyu Shin *
\nJournal of Fluorine Chemistry 2006, 127, 755\u00e2\u20ac\u201c759<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"

By courtesy of: Rajendra P. Singh, Jean\u00e2\u20ac\u2122ne M. Shreeve* Synthesis 2002, 17, 2561 and Olah’s reagent: Synthetic Methods and Reactions. 63.\u00e2\u20ac\u2122 Pyridinium Poly( hydrogen fluoride) (30% Pyridine-70% Hydrogen Fluoride): A Convenient Reagent for Organic Fluorination Reactions George A. Olah,* John T. Welch, Yashwant D. Vankar, Mosatomo Nojima, Istvan Kerekes, and Judith A. Olah J. Org. … Continue reading “Recent Advances in Nucleophilic Fluorination Reactions of Organic Compounds Using Deoxofluor and DAST”<\/span><\/a><\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[5,7],"tags":[],"class_list":["post-635","post","type-post","status-publish","format-standard","hentry","category-functionalization","category-soft"],"_links":{"self":[{"href":"https:\/\/softbeam.net\/research\/index.php?rest_route=\/wp\/v2\/posts\/635","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/softbeam.net\/research\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/softbeam.net\/research\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/softbeam.net\/research\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/softbeam.net\/research\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=635"}],"version-history":[{"count":0,"href":"https:\/\/softbeam.net\/research\/index.php?rest_route=\/wp\/v2\/posts\/635\/revisions"}],"wp:attachment":[{"href":"https:\/\/softbeam.net\/research\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=635"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/softbeam.net\/research\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=635"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/softbeam.net\/research\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=635"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}